Carbyne shows its strength
نویسندگان
چکیده
منابع مشابه
Photochemistry of Osmium-Carbyne Complexes
Upon charge transfer (Os to carbyne) excitation the carbyne complexes Os(CPh)(CO)(PPh3)2Cl and [Os(CPh)(CO)2(PPh3)2]+ with Ph = C6H5 are converted to the carbene complex Os(CHPh)(CO)(PPh3)2Cl2 in solutions containing HCl. It is suggested that the relaxed CT state can be described as square-pyramidal Os(II) complex containing a bent carbyne ligand which carries a lone pair at the coordinating ca...
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ژورنال
عنوان ژورنال: Nature Nanotechnology
سال: 2013
ISSN: 1748-3387,1748-3395
DOI: 10.1038/nnano.2013.247